Consider a particle in a one-dimensional quantum system with a potential energy function given by:
V(x)={0V0for 0≤x<afor x≥a
where a is a positive constant and V0 is a positive constant greater than zero.
a) Sketch the potential energy function V(x). Make sure to label the axis appropriately.
b) Determine the energy levels and corresponding wave functions for this system. Provide a qualitative sketch for the lowest energy level.
c) Calculate the probability of finding the particle in the region 0≤x≤a when it is in the lowest energy level. Express your answer in terms of the constants provided.
Assume the particle has mass m and the total energy in the system is less than V0.
Answer:
a) The potential energy function V(x) is given by:
V(x)={0V0for 0≤x<afor x≥a
The potential is zero when 0≤x<a and V0 when x≥a. Below is a sketch of the potential energy function:
| V0
|
| --
| --
| --
| --
|---------
| 0 a
b) To determine the energy levels and corresponding wave functions for this system, we need to solve the time-independent Schrödinger equation:
−2mℏ2dx2d2ψ+V(x)ψ=Eψ
Inside the region 0≤x<a, the potential energy is zero, so the Schrödinger equation becomes:
−2mℏ2dx2d2ψ=Eψ
Solving this differential equation, we get:
dx2d2ψ=−ℏ22mEψ
The general solution to this equation is:
ψ(x)=Asin(kx)+Bcos(kx)
where k=ℏ2mE and A and B are constants.
Inside the region x≥a, the potential energy is V0. So the Schrödinger equation becomes:
−2mℏ2dx2d2ψ+V0ψ=Eψ
Solving this differential equation, we get:
ψ(x)=Ce−αx+Deαx
where α=ℏ2m(V0−E) and C and D are constants.
To determine the energy levels and wave functions, we need to apply boundary conditions. The wave function must be continuous at x=a and its derivative must be continuous as well:
ψ(a−)=ψ(a+)ψ′(a−)=ψ′(a+)
From these boundary conditions, we can determine the energy levels and corresponding wave functions.
c) Given that the particle is in the lowest energy level, its wave function takes the form:
ψ(x)=Asin(kx)
where A is a constant.
The probability of finding the particle in the region 0≤x≤a is given by:
P=∫0a∣ψ(x)∣2dx
Substituting the wave function, we get:
P=∫0a∣Asin(kx)∣2dxP=∫0aA2sin2(kx)dx
Since ∣sin(kx)∣2=sin2(kx), we can simplify the integral:
P=A2∫0asin2(kx)dx
Using the trigonometric identity sin2(x)=21−21cos(2x), we further simplify the integral: